Ref: http://wiki.zimbra.com/wiki/Improving_Anti-spam_system#Postfix_whitelist_when_using_RBL.27s
As root, edit /opt/zimbra/conf/postfix_recipient_restrictions.cf, under reject_unauth_destination,
add check_client_access hash:/opt/zimbra/conf/postfix_rbl_override, like:
... reject_unauth_destination check_client_access hash:/opt/zimbra/conf/postfix_rbl_override reject_unlisted_recipient ...
Then:
su - zimbra -c 'zmmtactl restart'
Run as user zimbra, add address to /opt/zimbra/conf/postfix_rbl_override:
su - zimbra cd /opt/zimbra/conf/ nano postfix_rbl_override postmap hash:postfix_rbl_override